A current of 0.5 amp is passed through excess of molten mixture of `Al_(2)O_(3)` and `Na_(3)AlF_(6)` for 9.65 hours. The mass of Al (in mg) deposited at the cathode, with (100/12)% current efficiency is (Al = 27).
Let x g of `NaHCO_(3)` be present in the mixture?
Mass of `Na_(2)CO_(3)` in the mixture=(1.025-x)g`
Number of moles of `NaHCO_(3)=(x)/(84)`
Number of moles of `Na_(2)CO_(3)`=(1.0235-x)/(106)`
Number of moles of...
The reaction taking place at anode is :
`underset(71.0 g)(2Cl^(-)) rarr underset((71.0 g),("1 mole"))(Cl_(2))+underset(2xx96500" coulomb")(2e^(-))`
`Q=I xx t=100 xx 5xx 60xx 60` coulomb
The amount of chlorine liberated by passing...
Correct Answer - C
`underset(1" mole")(Na^(+))+underset(1" faraday")(e^(-)to)Na(s)`
`AP^(+)+underset(1" faraday")(3e^(-)to)Al(s)`
No. of mole of `Al=(1)/(3)` mole