`Fe^(2+) (aq)+NO_(3)^(-) (aq)+H_(2)SO_(4) (conc.) to` Brown ring
The brown ring is due to the formation of complex, `[Fe(H_(2)O)_(5)NO]SO_(4)`. What is the oxidation state of iron in the complex ?
Correct Answer - C
Since `HNO_(3)` is also a strong oxidising agent, therefore, aniline forms tarry oxidation products along with some oxidation products.
Dilute `H_(2)SO_(4)` behaves as a proton acid and zinc metal displaces hydrogen from the acid.
`Zn+H_(2)SO_(4)("dil")to ZnSO_(4)+H_(2)`
Concentrated `H_(2)O_(4)` behaves as a strong oxidising agent and itself is reduced to...
Correct Answer - B
`2NO_(3)^(-)+4H_(2)SO_(4)+6Fe^(2+)to6Fe^(3+)+2NOuarr+4SO_(4)^(2-)+4H_(2)O`
`Fe^(2+)+NOuarr +SO_(4)^(2-) to [Fe(NO)]^(2+)SO_(4)^(2-)`