The reason for greater range of oxidation states in actinoids is attributed to :
(1) actinoid contraction
(2) 5f, 6d and 7s levels having comparable energies
(3) 4f and 5d levels being close in energies
(2) Minimum or comparable energy gap between 5f, 6d and 7s subshell makes electron excitation easier, hence there is a greater range of oxidation states in actinoids.
[Hint : (a) Due to inert pair effect.
(b) Due to more bond dissociation enthalpy of O H as compared to S H bond.
(c) Due to more steric hindrance...
(i) Electronic configuration
The general electronic configuration for lanthanoids is [Xe]54 4f0-14 5d0-1 6s2 and that for actinoids is [Rn]86 5f1-14 6d0-1 7s2. Unlike 4f orbitals, 5f orbitals are not deeply...
Electronic configuration
The general electronic configuration for lanthanoids is [Xe]54 4f0-14 5d0-1 6s2 and that for actinoids is [Rn]86 5f1-14 6d0-1 7s2. Unlike 4f orbitals, 5f orbitals are not deeply buried...
(a) : As the distance between the nucleus and 5f orbitals (actinides) is more than the distance between the nucleus and 4f orbitals (lanthanides) hence the hold of nucleus on...
(c) : Actinoids show different oxidation states such as +2, +3, +4, +5, +6 and +7. However +3 oxidation state is most common among all the actinoids. The wide range...
Characteristics
Lanthanoids
Actinoids
(i) Electronic configuration
[Xe] 4f 1-145d0-16s2
[Rn] 5f 1-14 6d0-17s2
(ii) Oxidation states
Besides + 3 O.S. lanthanoids show +2 and +3 O.S. only in a
few...