Calculate heeat of formation of cane sugar following data:
`H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(g),DeltaH=-68.4` kcal
`C(g)+O_(2)(g)toCO_(2)(g),DeltaH=-94.4kcal`
`C_(12)H_(22)O_(11)(s)+12O_(2)(g)to12CO_(2)(g)+11H_(2)O(l),DeltaH=-1350.0kcal`
Correct Answer - A
`C("graphite")+O_(2)(g)toCO_(2)(g),DeltaH^(@)=-393.5kJ`
`underline(CO_(2)(g)toC("diamond")+O_(2)(g)," "DeltaH^(@)=+395.4kJ)`
On adding, `underline(C"graphite")toC("diamond"),DeltaH^(@)=+1900J=+1.9kJ)`
We have to calculate of `Delta H` for the reaction
`6 C(s)+3H_(2)(g)rarrC_(6)H_(6)(g)`
For reactant:
Heat of atomisation of `6` moles of `C=6xx170.9 kcal`
heat of atomisation of `6` moles of...
Correct Answer - C
From the given equations:
`C_(("graphite"))+O_(2)(g)toCO_(2)(g),Delta_(r)H^(@)=-393.5Kj" "Mol^(-1)`
`2H_(2)(g)+O_(2)(g)to2H_(2)O(l),Delta_(r)H^(@)=-285.8xx2kJ" "mol^(-1)`
`CO_(2)(g)+2H_(2)O(l)toCH_(4)(g)+2O_(2)(g),Delta_(r)H^(@)=+890.3kJ" "mol^(-1)`
Adding above three equations we get
`C_(("Graphite"))+2H_(2)(g)toCH_(4)(g)`
`Delta_(r)H^(@)=-393.5-285.8xx2+890.3`
`=74.8kJ" "mol^(-1)`.