What current is to be passed for `0.25` sec for deposition of certain weight of metal which is equal to its electrochemical equivalent ?
A. 4A
B. 100A
C. 200A
D. 2A
Correct Answer - B
Equivalents of metal=Equivalents of metal sulphate
`("wt.of metal")/("Eq. wt. of metal")("wt. of metal sulphate")/("Eq. wt. metal sulphate")`
`(2)/(x)=(6.8)/(x +48)`
`6.8x=2x+96`
`4.8x=96`
`x=(96)/(4.8)=20`
Correct Answer - A
At mass of element `= 20xx3=60`
Formula of its oxide is `M_(2)O_(3)`
`:.` Molecular mass of its oxide
`= 2xx60+16xx3`
`= 120 + 48 = 168`
Correct Answer - D
1000 mL 0.1 NHCl = 0.1 g eq of metal carbonate `=2gxx10=20g`
1 g eq of HCl is neutralized by 1 g eq. of metal carbonate
`=(20)/(0.1)=200`
Correct Answer - B
Atomic mass of metal = Eq. mass `xx` valency
`=20xx2=40`
Molecular formula of anhydrous chloride `=MCl_(2)`
Molecular mass of chloride `=40+2+xx35.5 =111`