Among the second period elements, the actual ionization enthalpies are in order:

Li

Explain why

(i). Be has higher first ionization enthalpy than B?

(ii). O has lower first ionization enthalpy than N and F?


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(a).He has higher first ionization enthalpy than B because Be has more stable electronic configuration 1s2 2s2 than B 1s2 2s2 2p1

(b). ∆iH1 of O is expected to be more than that of N but is actually lesser because the electronic configuration of N is more symmetrical as well as stable in comparison to O.∆i H1 of O is less than that of F because the ionization enthalpy in general increases along a period.

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