Total internal reflection can take place only if
(a) light goes from optically rarer medium (smaller refractive index) to optically denser medium
(b) light goes from optically denser medium to rarer medium
(c) the refractive indices of the two media are close to each other
(d) the refractive indices of the two media are widely different.


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(b) light goes from optically denser medium to rarer medium

EXPLANATION: 

When the light goes from a denser medium to lighter medium, it goes away from the normal. When the angle of incidence is increased, the angle of refraction becomes 90°. It is the critical angle. Now if the angle is increased further, the phenomenon of refraction is changed to total internal reflection.