How can ethanol and ethanoic acid be differentiated on the basis of their physical and chemical properties?
Physical Properties:
Ethanoic acid | Ethanol |
1. Pungent smell | Pleasant smell |
2. Melting point 290 K | M.P. is 156 K |
3. Boiling point 391 K | B.P. is 351 K |
Chemical Properties:
Ethanoic acid | Ethanol |
1. Ethanoic acid + Sodium bicarbonate gives CO2 gas. | No CO2 gas produced. |
2. On addition of alk. KMnO4 the colour does not disappear. | On addition of alk. KMnO4 the colour disappear. |
Ethanol is a liquid at room temperature with a pleasant odour while ethanoic acid has vinegar-like smell. The melting point of ethanoic acid is 17°C. This is below room temperature and hence, it freezes during winters.
Ethanoic acid reacts with metal carbonates and metal hydrogencarbonates to form salt, water, and carbon dioxide gas while ethanol does not react with them.
Difference in physical properties:
Ethanol | Ethanoic acid |
---|---|
This is in liquid form at room temperature. Its melting point is 156° K. | Its melting point is 290K and hence it often freezes during winter in cold climates. |
Difference in chemical properties | |
Ethanol will not react with metallic carbonates. | Ethanoic acid reacts with carbonates and Hydrogen carbonate and forms salts, carbon dioxide and water. |