For the reaction, A = X + Y, the respective concentrations are C<sub>A</sub>, C<sub>X</sub> and C<sub>Y</sub>. The forward reaction rate constant is kf and the backward reaction rate constant is kb. Choose the correct statement from the following:<br>P. At equilibrium, kf C<sub>A</sub> &gt; k<sub>B</sub> CxCy<br>Q. If the reaction is irreversible than, kb C<sub>X</sub>C<sub>Y</sub> = 0<br>R. The backward reaction rate will essentially be first order, if the forward reaction rate is first order.<br>S. Activation energy for the first order forward reaction will be independent of temperature.

Correct Answer: Q, R