Which of the following will be the longest wavelength in Balmer series of hydrogen atom?

Correct Answer: 6557 Å
The Balmer series of spectral lines occur when electrons transition from an energy level higher than n = 2 back down to n = 1. Therefore, the longest wavelength in Balmer series is n1 = 2 and n2= 3 is 1/π=\(R\),R=1.1×10 m-1. Thus, 6557 Å will be the longest wavelength.